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MSDS For more permethrin information click here For Emergency Assistance involving chemicals call - CHEMTREC (800) 424-9300
The Version Date for this MSDS is : 01/22/1998
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PRODUCT IDENTIFICATION
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PRODUCT NAME: PRENTOX EXCITE
MSDS#: P19136VS
DATE ISSUED: 1/5/98
SUPERSEDES: 12/13/96
ISSUED BY: 009823
Section 1: Chemical Identification
Product: 655-798 Prentox ExciteR"
EPA Signal Word: CAUTION
Active Ingredients (%):
Pyrethrins (6%) (CAS # 8003-34-7)
Piperonyl Butoxide Technical (60.0%) (CAS# 51-03-6)
Chemical Class: Insecticide mixture
Section 2: Composition Information on Ingredients
OSHA ACGIH NTP/IARC/OSHA.
Material: PEL TLV Other Carcinogen
Pyrethrins Not Est. (TWA) 5 mg/m3 Not Est. No
Piperonyl Butoxide Technical Not Est. Not Est. Not Est. No
Emulsifier (CAS# -
Supplier confidential) Not Est. Not Est. Not Est. No
Petroleum solvent (CAS # 64742-47-8) (TWA) 300 ppm*
*Supplier recommendation
Section 3: Hazards Identification
Symptoms of Acute Exposure
Ingestion: May cause gastrointestinal effects, such as nausea, cramps,
vomiting and diarrhea.
Ingestion of large quantities can result in nervous system effects, such as
dizziness, loss of coordination, tremors, and loss of consciousness. Symptoms
usually regress with no long lasting effects. At high oral doses, the type of
solvent in this product has caused irreversible damage to the
liver and kidney (male only) in rats. These effects are not relevant to humans
at occupational levels of exposure.
Eyes: May cause temporary eye irritation.
Skin: May be irritating to skin. Repeated contact may cause dermatitis.
Inhalation: May cause nasal and respiratory irritation at high concentrations.
Medical Conditions Generally Aggravated by Exposure: None known.
Section 4: First Aid Measures
Ingestion: Do not induce vomiting. This product contains a petroleum solvent.
Vomiting may cause aspiration pneumonia. Call a physician or Poison Control
Center immediately.
Inhalation: Remove victim to fresh air. Administer artificial respiration if
necessary.
Eye Contact: Flush eyes with plenty of water for 15 minutes. Call a physician
if irritation persists.
Skin Contact: Remove contaminated clothing and wash affected areas with soap
and water. Contact a physician if irritation persists.
Section 5: Fire Fighting Measures
Fire and Explosion
Flash Point (Method Used): 154 F. (Closed cup)
Flammable Limits: LEL: 0.6
UEL: 7.0 (solvent)
In case of fire: Use CO2, foam, dry chemical, or sand extinguishing media. Do
not inhale smoke or vapors Use self-contained breathing apparatus and wear
full protective clothing. Evacuate non-
essential personnel from the area to prevent human exposure to fire, smoke,
fumes or products of combustion. Prevent use of contaminated buildings, area
and equipment until decontaminated. This product is toxic to fish, birds and
other wildlife, prevent spread of contaminated runoff.
Unusual Fire and Explosion Hazards: Combustible liquid. Keep containers cool
to avoid explosive ignition.
Accidental Release Measures
Wear chemical safety glasses with side shields or chemical goggles, chemical
resistant gloves, such as barrier laminate, nitrite rubber, neoprene rubber or
viton, shoes and socks, long-sleeved shirt and
long pants to prevent contact with the product or its vapors. Cover the
spilled area with generous amounts of absorbent material, such as clay,
diatomaceous earth, sand or sawdust. Sweep the
contaminated absorbent onto a shovel and put the sweepings into a salvage
drum. Wash the spill area with water containing a strong detergent, absorb the
rinsate, sweep up and put into salvage drum.
Dispose of wastes as below.
Waste disposal method: Wastes resulting from the use of this product may be
disposed of on site or at an approved waste disposal facility. This product is
toxic to fish, birds and other wildlife. Do not contaminate the environment
through improper disposal.
Section 7: Handling and Storage
Do not use or store near heat or open flame. Exposure to temperatures above
130 F. may cause bursting of containers. Store in a well ventilated, secure
area, out of reach of children, domestic animals Do not contaminate water,
food or feed by storage or disposal. Periodically inspect stored
materials. Prevent eating, drinking, tobacco usage and cosmetic application in
areas where there is a potential for exposure to the material. Always wash
thoroughly after handling
Section 8: Exposure Controls/Personal Protection
Ingestion: Prevent eating, drinking, tobacco usage and cosmetic application in
areas where there is a potential for exposure to the material. Always wash
thoroughly after handling.
Eye contact: To avoid eye contact, wear safety glasses with side shields or
chemical goggles.
Skin Contact: To avoid skin contact, wear chemical resistant gloves, such as
barrier laminate, nitrite rubber, neoprene rubber or viton, shoes and socks,
long-sleeved shirt and long pants
Inhalation: To avoid breathing vapors or mist, wear a NIOSH approved chemical
cartridge respirator with organic vapor cartridges and a pesticide pre-
filter. or a supplied air respirator.
Section 9: Physical and Chemical Properties
Appearance: Yellow to amber liquid.
Odor: Pleasant woody odor.
Melting Point: Not applicable.
Boiling Point: Not determined.
Specific Gravity (H2O = 1): 0.9930
pH: Not applicable.
Solubility In Water: Emulsifies.
Vapor Pressure: Not determined.
Section 10: Stability and Reactivity
Reactivity:
Stability: Stable
Hazardous Polymerization: Will not occur
Conditions to avoid: Flame, ignition sources, strong acids, and alkalies
Hazardous Decomposition Products: None known.
Section 11: Toxicological Information
Acute toxicity/irritation studies:
Pyrethrins (58%):
Ingestion: Slightly toxic Oral LD50 (Rat) 2,370 mg/kg (58% pyrethrins)
Dermal: Slightly toxic Dermal LD50 (Rabbit) >2,000 mg/kg (58% pyrethrins)
Inhalation: Slightly toxic Inhalation LC50 3.4 mg/L (58% pyrethrins)
Eye Contact: Minimally irritating (Rabbit)
Skin Contact: Minimally irritating (Rabbit)
Skin Sensitization: Not a sensitizer (Guinea Pig)
Mutagenic Potential: Pyrethrins - none observed.
Reproductive Hazard Potential: Pyrethrins - none observed.
Chronic/Subchronic Toxicity: Pyrethrins - none observed.
Carcinogenic Potential: Pyrethrins - marginal increases in benign thyroid,
parathyroid, ovary and liver tumors were observed in rats and in the lungs of
mice, following lifetime high dose exposures to pyrethrins. The significance
of this observation is questionable and under review. The
doses at which tumors were observed for pyrethrins greatly exceeded potential
human exposures from labeled uses. Doses at which these effects were observed
greatly exceed anticipated human dietary intake. At anticipated dietary
exposure levels, it is highly unlikely that this product would result in
carcinogenic effects.
Other toxicity information: Not available.
Piperonyl Butoxide (technical grade):
Acute toxicity/irritation studies:
Ingestion: minimally toxic Oral LD50 (rat): 4570 mg/kg - males
7220 mg/kg - females
Dermal:Slightly toxic Dermal LD50 (rabbit) >2000 mg/kg
Inhalation: Slightly toxic Inhalation LC50 .5.9 mg/l
Eye Contact: Slightly irritating (rabbit)
Skin Contact: Minimally irritating (rabbit)
Skin Sensitization: not a sensitizer (guinea pig)
Mutagenic Potential: none observed
Reproductive Hazard Potential: none observed
Chronic/Subchronic Toxicity: none observed
Carcinogenic Potential: Marginally higher incidences of benign liver tumors in
mice were observed following lifetime high dose exposures to Piperonyl
Butoxide. The significance of this observation is questionable and under
review. The doses at which tumors were observed greatly
exceeded potential human exposure from labeled uses. Doses at which the
effects were observed greatly exceeded human dietary intake. At anticipated
dietary exposure levels, it is highly unlikely
that this product would result in carcinogenic effects.
Other toxicity information:
Mutagenicity: Piperonyl Butoxide was not genotoxic in several tests, including
the Ames mutagenicity assay, chromosome aberration in Chinese hamster ovary
(CHO) cells, CHO/HGPRT assay with S9 activation, and in the unscheduled DNA
synthesis (UDS) assay in cultured human liver cells.
Teratology/Reproductive effects: There were no birth defects or adverse
effects on reproductive parameters in rats or rabbits. Piperonyl Butoxide is
not considered to be teratogenic.
Toxicity of other components:
Emulsifier: The supplier notes that the emulsifier may cause severe eye
irritation from contact.
Also, prolonged skin contact with soaked clothing may cause irritation.
Inhalation may cause chest pain and coughing. Ingestion may cause nausea,
vomiting and diarrhea. The supplier does not note any chronic toxicity.
Petroleum solvent: The supplier reports that overexposure to this solvent may
cause kidney damage. Exposure to the liquid may cause eye irritation and mild
skin irritation. Breathing can cause nasal and respiratory irritation, central
nervous system effects including dizziness, weakness, fatigue, nausea,
headache, possible unconsciousness and even death. Swallowing
can cause gastrointestinal irritation, nausea, vomiting and diarrhea.
Aspiration into the lungs can cause aspiration pneumonia, which can be fatal.
Target Organs:
Active Ingredients: Central nervous system
Inert Ingredients:
Emulsifier: Eyes, skin, respiratory tract.
Petroleum Solvent: Respiratory tract, central nervous system and skin.
Section 12: Ecological information
Summary Or Effects: Pyrethrins are highly toxic to fish and aquatic organisms.
Eco-Acute Toxicity:
Pyrethrins (58%) Rainbow trout 96-hour LC50: 5.2 ug/l
Bluegill sunfish 96-hour LC50: 10 ug/l
Honeybee Acute: 0.022 ug/bee
Daphnia magna 48-hour LC50: 12 ug/l
Bobwhite Quail Oral LD50: >2000 mg/kg
Bobwhite 5 day dietary LC50: >5620 ppm
Mallard 5 day dietary LC50: >5620 ppm
Piperonyl Butoxide (technical grade):
Rainbow Trout 96-hour LC50: 6.12 ppm
Bluegill Sunfish 96-hour LC50: 5.37 ppm
Daphnia Magna 48-hour LC50: 0.51 ppm
Honeybee Acute: >25 ug/bee
Bobwhite Quail Oral LD50: >2250 mg/kg
Bobwhite 5 day dietary LC50: >5620 ppm
Mallard 5 day dietary LC50: >5620 ppm
Eco-Chronic Toxicity:
Pyrethrins (58%)
Fish (Fathead Minnow) Early life stage MATC: > 1.9 ug total pyrethrins/L
Invertebrate (Daphnia Magna) Life cycle MATC: 1.3 ug total pyrethrins/L
Piperonyl Butoxide (technical grade):
Fish (Fathead Minnow) Early life stage MATC: >0.18 mg/L - <0.42 mg/L
- Invertebrate (Daphnia Magna) life cycle MATC: > 30 ug/L - <47 ug/L
Environmental Fate: Not available
Section 13: Disposal Considerations
Disposal: do not reuse product containers. Dispose of product containers,
waste containers, and residues according to Federal, State and local health
and environmental regulations.
Characteristic Waste: Ignitable.
Listed Waste: None.
Section 14: Transport Information
DOT Classification: COMBUSTIBLE LIQUID, N.O.S. (PETROLEUM NAPHTHA), NA1993,
PGIII, RQ (PYRETHRINS)
B/L Freight Classification: INSECTICIDES; OTHER THAN POISON, NMFC ITEM 102120
International Transportation: Not available.
Section 15: Regulatory Information
SARA Title III Classification:
Section 311/312:
Acute health hazard
Fire hazard
Section 313 Chemicals: Piperonyl Butoxide Technical (60.096)
This product contains a toxic chemical or chemicals subject to the reporting
requirements of Section 313 Or Title III and Or 40 CFR 372. Any copies or
redistribution of this MSDS must include this notice.
Proposition 65: Not applicable.
CERCLA Reportable Quantity (RQ): 16.67 lb.
RCRA Classification: Ignitable
TSCA Status: Exempt from TSCA.
Section 16: Other Information
NFPA Hazard Ratings:
Health: 1
Flammability: 2
Reactivity: 0
For Additional Information:
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